Processing

How Decaf Coffee Is Made—and How It Differs From Low-Caffeine Varieties

Decaf usually means most caffeine was removed from green coffee before drying and roasting. Common methods use water, solvents, or carbon dioxide, leaving some caffeine in the finished coffee. This differs from varieties with genetically lower caffeine content.

Decaf processing that removes caffeine from green beans compared with a coffee plant that is genetically lower in caffeine

Washed Process

  1. Pick ripe coffee cherries
  2. Remove the skin and pulp
  3. Break down the mucilage through fermentation
  4. Wash the coffee
  5. Dry the parchment coffee

Natural Process

  1. Pick ripe coffee cherries
  2. Dry the whole cherries
  3. Turn them regularly
  4. Remove the dried fruit and parchment
  5. Prepare the green coffee

Honey Process

  1. Pick ripe coffee cherries
  2. Remove the skin while retaining some mucilage
  3. Dry the coffee with mucilage attached
  4. Remove the parchment after drying
  5. Prepare the green coffee

Wet-Hulled Process

  1. Pick ripe coffee cherries
  2. Depulp, then briefly ferment or wash
  3. Remove the parchment while moisture remains high
  4. Continue drying
  5. Prepare the green coffee

Anaerobic Fermentation

  1. Pick ripe coffee cherries
  2. Place the coffee in a sealed or low-oxygen vessel
  3. Control fermentation time and temperature
  4. Finish with a washed, natural, or honey process
  5. Dry the coffee

What decaf means on a coffee bag

Decaf or decaffeinated usually means most caffeine was removed from green coffee before drying and roasting. Processing before roasting avoids removing the aromas developed during roasting along with the caffeine.

Decaf retains some caffeine, and selectively removing caffeine without other soluble compounds remains difficult. The National Coffee Association reports typical removal of about 97%, comparing about 95 milligrams per 8-ounce cup of regular coffee with about 2 to 15 milligrams in decaf. USDA reference data give about 1 milligram per 100 grams of brewed decaf, equivalent to about 2 milligrams in 8 fluid ounces, while The Conversation cites about 7 milligrams. These are different reference figures; actual amounts vary with the lot and brewing method.

For amounts in different drinks and daily intake references, see caffeine.

It is not a low-caffeine variety

A low-caffeine variety has genetically lower caffeine content. Laurina, also called Bourbon Pointu, is a familiar example; the literature often describes these varieties as containing about half as much caffeine as other arabica cultivars.

Decaffeination is an additional treatment of green coffee. A lot can list both its variety and its decaf status, describing the plant and the subsequent treatment respectively.

Washed, natural, and honey processing describe how coffee fruit becomes green coffee. Decaffeination takes place after that green coffee has been prepared.

Three common methods

All three methods begin with moistened green beans, which are dried after decaffeination and then roasted.

Three common decaf routes shown as water process, solvent, and carbon dioxide
The conceptual diagram compares water, solvent, and carbon dioxide methods, all applied to unroasted green coffee.

Solvent methods use methylene chloride or ethyl acetate. Producers can put solvent on the beans, or they can move solubles into water first and treat that water. The Conversation describes this route as removing about 96% to 97%. A sugarcane-process label usually means ethyl acetate, which can be made from fermented sugarcane; industrial ethyl acetate is not always from cane. Treat that as marketing language, not proof that “natural” tastes better.

Swiss Water® is one example of water processing, trademarked by a Vancouver company that uses water, Green Coffee Extract, and carbon filters. The company describes its coffee as 99.9% caffeine free, while The Conversation reports caffeine removal of about 94% to 96% for Swiss water. These source figures differ, and water processing includes other methods and brands. That branded method is in the Swiss Water Process.

High-pressure carbon dioxide methods date from the early 1970s and are relatively selective for caffeine. The Conversation reports removal of about 96% to 98%, describing costly equipment and common use for supermarket decaf.

Because other solubles leave with the caffeine, cupping notes on older commodity solvent decaf often call it flatter and more muted. Specialty lots more often use water, CO₂, or ethyl acetate. That is a common current approach, not a ranking of which method tastes better.

Regular coffee compared with decaf, which still contains a little caffeine
Decaf retains some caffeine, with amounts varying by lot and brewing method. The conceptual diagram does not represent fixed milligram values.

How to read the name on a bag

Decaf identifies an additional green-coffee treatment; variety and washed or natural processing describe different information. Bags may omit the decaffeination method, and coffee without a Swiss Water® label can still use another water process. A solvent or sugarcane label alone cannot predict sensory quality.

In the EU, soluble coffee labeled decaffeinated has an anhydrous-caffeine cap of 0.3% of coffee-based dry matter. A 0.1% roasted-bean threshold is often a national rule, not one EU roasted-coffee statute. How much you ingest still depends on dose, brew, and cup size. This page is not medical advice.

Common Misconceptions

  • Is decaf caffeine-free?

    Decaf still contains some caffeine. The National Coffee Association lists about 2–15 mg per typical cup, while USDA reference data give about 2 mg in an 8-ounce serving. Actual amounts vary by source, lot, and brewing method.

  • Is that the same as a low-caffeine variety?

    Decaf describes caffeine removal from green coffee, while a low-caffeine variety such as Laurina has genetically lower caffeine content. These varieties usually still contain some caffeine.

  • Should I always choose Swiss Water?

    Swiss Water® is one branded water process. Origin, roasting, and brewing also affect quality, so the brand or method alone cannot establish which coffee will taste better.

  • Does solvent decaf mean the coffee is unsafe?

    U.S. rules limit methylene chloride residue in roasted decaf to 10 ppm. Sugarcane processing usually refers to ethyl acetate, a different solvent that is not always made from sugarcane. A clinician can address concerns related to individual health conditions.

  • Does a decaf label guarantee how the coffee was processed?

    No. Bags often omit the method. A missing Swiss Water name does not mean water was not used; a solvent or sugarcane label does not decide the cupping score.

Sources and Notes